25,523 research outputs found

    Anisotropic superconducting properties of aligned Sm0.95_{0.95}La0.05_{0.05}FeAsO0.85_{0.85}F0.15_{0.15} microcrystalline powder

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    The Sm0.95_{0.95}La0.05_{0.05}FeAsO0.85_{0.85}F0.15_{0.15} compound is a quasi-2D layered superconductor with a superconducting transition temperature Tc_c = 52 K. Due to the Fe spin-orbital related anisotropic exchange coupling (antiferromagnetic or ferromagnetic fluctuation), the tetragonal microcrystalline powder can be aligned at room temperature using the field-rotation method where the tetragonal ab\it{ab}-plane is parallel to the aligned magnetic field Ba_{a} and c\it{c}-axis along the rotation axis. Anisotropic superconducting properties with anisotropic diamagnetic ratio χc/χab\chi_{c}/\chi_{ab}\sim 2.4 + 0.6 was observed from low field susceptibility χ\chi(T) and magnetization M(Ba_{a}). The anisotropic low-field phase diagram with the variation of lower critical field gives a zero-temperature penetration depth λc\lambda_{c}(0) = 280 nm and λab\lambda_{ab}(0) = 120 nm. The magnetic fluctuation used for powder alignment at 300 K may be related with the pairing mechanism of superconductivity at lower temperature.Comment: 4 pages, 6 figure

    Predicting floods in a large karst river basin by coupling PERSIANN-CCS QPEs with a physically based distributed hydrological model

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    In general, there are no long-term meteorological or hydrological data available for karst river basins. The lack of rainfall data is a great challenge that hinders the development of hydrological models. Quantitative precipitation estimates (QPEs) based on weather satellites offer a potential method by which rainfall data in karst areas could be obtained. Furthermore, coupling QPEs with a distributed hydrological model has the potential to improve the precision of flood predictions in large karst watersheds. Estimating precipitation from remotely sensed information using an artificial neural network-cloud classification system (PERSIANN-CCS) is a type of QPE technology based on satellites that has achieved broad research results worldwide. However, only a few studies on PERSIANN-CCS QPEs have occurred in large karst basins, and the accuracy is generally poor in terms of practical applications. This paper studied the feasibility of coupling a fully physically based distributed hydrological model, i.e., the Liuxihe model, with PERSIANN-CCS QPEs for predicting floods in a large river basin, i.e., the Liujiang karst river basin, which has a watershed area of 58 270 km-2, in southern China. The model structure and function require further refinement to suit the karst basins. For instance, the sub-basins in this paper are divided into many karst hydrology response units (KHRUs) to ensure that the model structure is adequately refined for karst areas. In addition, the convergence of the underground runoff calculation method within the original Liuxihe model is changed to suit the karst water-bearing media, and the Muskingum routing method is used in the model to calculate the underground runoff in this study. Additionally, the epikarst zone, as a distinctive structure of the KHRU, is carefully considered in the model. The result of the QPEs shows that compared with the observed precipitation measured by a rain gauge, the distribution of precipitation predicted by the PERSIANN-CCS QPEs was very similar. However, the quantity of precipitation predicted by the PERSIANN-CCS QPEs was smaller. A post-processing method is proposed to revise the products of the PERSIANN-CCS QPEs. The karst flood simulation results show that coupling the post-processed PERSIANN-CCS QPEs with the Liuxihe model has a better performance relative to the result based on the initial PERSIANN-CCS QPEs. Moreover, the performance of the coupled model largely improves with parameter re-optimization via the post-processed PERSIANN-CCS QPEs. The average values of the six evaluation indices change as follows: the Nash-Sutcliffe coefficient increases by 14 %, the correlation coefficient increases by 15 %, the process relative error decreases by 8 %, the peak flow relative error decreases by 18 %, the water balance coefficient increases by 8 %, and the peak flow time error displays a 5 h decrease. Among these parameters, the peak flow relative error shows the greatest improvement; thus, these parameters are of page1506 the greatest concern for flood prediction. The rational flood simulation results from the coupled model provide a great practical application prospect for flood prediction in large karst river basins

    Synergetic regulation of translational reading-frame switch by ligand-responsive RNAs in mammalian cells

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    Distinct translational initiation mechanisms between prokaryotes and eukaryotes limit the exploitation of prokaryotic riboswitch repertoire for regulatory RNA circuit construction in mammalian application. Here, we explored programmed ribosomal frameshifting (PRF) as the regulatory gene expression platform for engineered ligand-responsive RNA devices in higher eukaryotes. Regulation was enabled by designed ligand-dependent conformational rearrangements of the two cis-acting RNA motifs of opposite activity in -1 PRF. Particularly, RNA elements responsive to trans-acting ligands can be tailored to modify co-translational RNA refolding dynamics of a hairpin upstream of frameshifting site to achieve reversible and adjustable -1 PRF attenuating activity. Combined with a ligand-responsive stimulator, synthetic RNA devices for synergetic translational-elongation control of gene expression can be constructed. Due to the similarity between co-transcriptional RNA hairpin folding and co-translational RNA hairpin refolding, the RNA-responsive ligand repertoire provided in prokaryotic systems thus becomes accessible to gene-regulatory circuit construction for synthetic biology application in mammalian cells

    Intrapore-Texturized Vanadia-Hydrate Supercapacitor with Ultrahigh Area-Normalized Capacitance

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    A pressing need for ultrahigh area‐normalized capacitance emerges from the migration to miniaturized composite supercapacitors. Herein, an advanced electric field‐assisted sol–gel synthesis protocol that allows to obtain ribbon‐like vanadium oxides that preferentially creep along the porous tunnels in a commercially available carbon host of low density is demonstrated. In particular, this design offers 1) to convert the original submicrometer‐sized pore network into hierarchically macroporous yet 3D‐interconnected bicontinuous composite frameworks and 2) to considerably add pseudo‐capacitive functionalities onto a highly conductive carbon cloth backbone. Both are demonstrated by an unprecedented area‐normalized capacitance exceeding 5 F cm−2. Moreover, the as‐designed symmetric supercapacitor is characterized by a maximum area‐normalized cell capacitance in the order of 1 F cm−2, a geometric energy density of 0.34 mW h cm−2, and a geometric power density of 28.3 mW cm−2. These features outperform commercial double‐layer supercapacitors as well as many state‐of‐the‐art composite pseudo‐capacitors and lithium‐ion microbatteries

    Precise Pressure Dependence of the Superconducting Transition Temperature of FeSe: Resistivity and ^77Se--NMR Study

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    We report the precise pressure dependence of FeSe from a resistivity measurement up to 4.15 GPa. Superconducting transition temperature (T_c) increases sensitively under pressure, but shows a plateau between 0.5-1.5 GPa. The maximum T_c, which is determined by zero resistance, is 21 K at approximately 3.5 GPa. The onset value reaches ~37 K at 4.15 GPa. We also measure the nuclear spin-lattice relaxation rate 1/T_1 under pressure using 77Se--NMR measurement. 1/T_1 shows that bulk superconductivity is realized in the zero-resistance state. The pressure dependence of 1/T_1T just above T_c shows a plateau as well as the pressure dependence of T_c, which gives clear evidence of the close relationship between 1/T_1T and T_c. Spin fluctuations are suggested to contribute to the mechanism of superconductivity.Comment: 4pages, 6figures: to be published in J. Phys. Soc. Jpn. Vol.78 No.6 (2009
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